1356407-57-2Relevant academic research and scientific papers
Versatile synthesis of isocoumarins and α-pyrones by Ruthenium-catalyzed oxidative C - H/O - H bond cleavages
Ackermann, Lutz,Pospech, Jola,Graczyk, Karolina,Rauch, Karsten
, p. 930 - 933 (2012)
An inexpensive cationic ruthenium(II) catalyst enabled the expedient synthesis of isocoumarins through oxidative annulations of alkynes by benzoic acids. This C - H/O - H bond functionalization process also proved applicable to the preparation of α-pyrones and was shown to proceed by rate-limiting C - H bond ruthenation.
