1356536-79-2Relevant academic research and scientific papers
Quantitative Assessment of the Lewis Acidity of Silylium Ions
Gro?ekappenberg, Henning,Rei?mann, Matti,Schmidtmann, Marc,Müller, Thomas
, p. 4952 - 4958 (2015)
The Lewis acidity of several aryl-substituted tetrylium ions was classified experimentally by applying the Gutmann-Beckett method and computationally by calculation of fluoride ion affinities (FIA) (tetrel elements = Si, Ge). According to these measures,
A new synthesis of triarylsilylium ions and their application in dihydrogen activation
Schaefer, Andre,Reissmann, Matti,Schaefer, Annemarie,Saak, Wolfgang,Haase, Detlev,Mueller, Thomas
, p. 12636 - 12638 (2012/02/15)
Well-shuffled: An unexpected substituent distribution reaction via alkyldiarylsilylium ions leads to a distribution of substituents. Starting from alkyldiaryl silanes, this reaction provides a facile synthetic approach to sterically highly hindered triarylsilylium ions. These silylium ions can be applied in dihydrogen activation reactions. Copyright
