1356557-62-4

Basic information

• Product Name: exo-methyl 1-benzyloxycarbonyl-3a-bromo-8-tert-butyloxycarbonyl-1,2,3,3a,8,8a-hexahydropyrrolo[2,3-b]indole-2-carboxylate
• Synonyms: exo-methyl 1-benzyloxycarbonyl-3a-bromo-8-tert-butyloxycarbonyl-1,2,3,3a,8,8a-hexahydropyrrolo[2,3-b]indole-2-carboxylate
• CAS NO: 1356557-62-4
• Molecular Weight: 531.403
• Mol File: 1356557-62-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: exo-methyl 1-benzyloxycarbonyl-3a-bromo-8-tert-butyloxycarbonyl-1,2,3,3a,8,8a-hexahydropyrrolo[2,3-b]indole-2-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: exo-methyl 1-benzyloxycarbonyl-3a-bromo-8-tert-butyloxycarbonyl-1,2,3,3a,8,8a-hexahydropyrrolo[2,3-b]indole-2-carboxylate(1356557-62-4)
• EPA Substance Registry System: exo-methyl 1-benzyloxycarbonyl-3a-bromo-8-tert-butyloxycarbonyl-1,2,3,3a,8,8a-hexahydropyrrolo[2,3-b]indole-2-carboxylate(1356557-62-4)

Safety Data

• Hazardous Substances Data: 1356557-62-4(Hazardous Substances Data)

Upstream product

• 643751-42-2 N-carbobenzyloxy-1-tert-butoxycarbonyl-L-tryptophan methyl ester 
• 501-53-1 benzyl chloroformate 
• 7524-52-9 (S)-tryptophan methyl ester hydrochloride 

Downstream Products

• 1356557-80-6 C₄₅H₄₂N₄O₁₀ 

Relevant articles and documents

Orthogonal protecting groups in the synthesis of tryptophanyl- hexahydropyrroloindoles

The synthesis of various polycyclic systems containing aC 3a-Ni bond between a hexahydropyrrolo[2,3-b]indole and an indole tryptophan is described here. A series of experiments were performed to determine the best combination of five orthogonal protecting groups and the best reaction conditions for formation of said bond, which is a common feature among many recently discovered marine natural products.