135682-16-5Relevant academic research and scientific papers
Reactions of chiral 2-p-tolylsulfinycycloalkanones with AlMe3
Bueno, Ana B.,Carmen Carreno,Fischer, Jean,Garcia Ruano,Pena, Begona,Penas, Lorenzo,Rubio, Almudena
, p. 3191 - 3194 (2007/10/02)
The reactions of (S2,Rs) and (R2,Rs)-2-p-tolylsulfinylcyclohexanones with AlMe3/ZnClz only yield the cyclohexylmethylcarbinols with R configuration at hydroxylic carbon. The (R1,S2,Rs)-1-methyl-2-p-tolysulfinylcyclopentanol was the only compound obtained in the reaction of Me3Al with both epimeric 2-p-lolysulfinyleyclopentanones. The d.e. of both reactions are higher than 96%.
