1356825-70-1

Basic information

• Product Name: Cr(CO)4H₂AlNC₆H₃(CH(CH₃)2)2CCH₃CHCCH₃NC₆H₃(CH(CH₃)2)2
• CAS NO: 1356825-70-1
• Molecular Weight: 610.693
• Mol File: 1356825-70-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Cr(CO)4H₂AlNC₆H₃(CH(CH₃)2)2CCH₃CHCCH₃NC₆H₃(CH(CH₃)2)2(CAS DataBase Reference)
• NIST Chemistry Reference: Cr(CO)4H₂AlNC₆H₃(CH(CH₃)2)2CCH₃CHCCH₃NC₆H₃(CH(CH₃)2)2(1356825-70-1)
• EPA Substance Registry System: Cr(CO)4H₂AlNC₆H₃(CH(CH₃)2)2CCH₃CHCCH₃NC₆H₃(CH(CH₃)2)2(1356825-70-1)

Safety Data

• Hazardous Substances Data: 1356825-70-1(Hazardous Substances Data)

Upstream product

• 278608-73-4 [(HC(CMeN(2,6-i-Pr₂C₆H₃))2)AlH₂] 
• 199620-14-9 chromium⁽⁰⁾ hexacarbonyl 
• 12301-34-7 tetracarbonyl(η2:2-cyclooctadiene)chromium(0) 

Relevant articles and documents

σ-Alane complexes of chromium, tungsten, and manganese

Photolytic ligand displacement and salt metathesis routes have been exploited to give access to κ1 σ-alane complexes featuring Al-H bonds bound to [W(CO)5] and [Cp′Mn(CO) 2] fragments, together with a related κ2 complex of [Cr(CO)4]. Spectroscopic, crystallographic, and quantum chemical studies are consistent with the alane ligands acting predominantly as σ-donors, with the resulting binding energies calculated to be marginally greater than those found for related dihydrogen complexes.