1357010-28-6

Basic information

• Product Name: C₆(CH₃)3(C₅H₂N(C₅H₄N)2)3
• Synonyms: C₆(CH₃)3(C₅H₂N(C₅H₄N)2)3
• CAS NO: 1357010-28-6
• Molecular Weight: 813.964
• Mol File: 1357010-28-6.mol

Chemical Properties

• CAS DataBase Reference: C₆(CH₃)3(C₅H₂N(C₅H₄N)2)3(CAS DataBase Reference)
• NIST Chemistry Reference: C₆(CH₃)3(C₅H₂N(C₅H₄N)2)3(1357010-28-6)
• EPA Substance Registry System: C₆(CH₃)3(C₅H₂N(C₅H₄N)2)3(1357010-28-6)

Safety Data

• Hazardous Substances Data: 1357010-28-6(Hazardous Substances Data)

Upstream product

• 1122-62-9 2-acetylpyridine 
• 119198-88-8 2,4,6-trimethylbenzene-1,3,5-tricarbaldehyde 

Relevant articles and documents

New trinuclear dendritic complexes with [Ru(tpy)(bpy)X]n + (X = Cl, H2O; N = 1, 2) for enhanced water oxidation and light-driven alcohol oxidation

A symmetric trinuclear ruthenium complex with [Ru(tpy)(bpy)(Cl)]+ (tpy = 2,2′:6′,2″-terpyridine; bpy = 2,2′-bipyridine) connected by 2,4,5-trimethylbenzene was easily prepared. The complex showed effective chemical water oxidation and light-driven oxidation activity of alcohols to corresponding aldehydes in water. When Cl- is replaced by H2O, the resulting complex exhibited over a twofold increase in O2 evolution activity compared with its parent complex. Moreover, compared with equimolar ruthenium amounts of the mononuclear complex with the H2O ligand, the trinuclear ruthenium complex with the conjugated ligand motif also displayed a two time increase in water oxidation activity.

Shape-persistent, ruthenium(ii)- and iron(ii)-bisterpyridine metallodendrimers: Synthesis, traveling-wave ion-mobility mass spectrometry, and photophysical properties

A class of shape-persistent metallodendrimer has been developed through a self-assembly strategy, in which 〈tpy-RuII-tpy〉 or 〈tpy-FeII-tpy〉 connectivity is utilized, as branching moieties or nodes. These metallomacromolecules were fully characterized by 1H and 13C NMR, traveling wave ion mobility mass spectrometry (TWIM MS), single crystal X-ray, UV-vis absorption, photoluminescence, and cyclic voltammetry. Significant increase in the drift times of the same charge states was observed with increasing generation of these complexes, which is in line with the change of molecular size. Moreover, the photophysical properties (molar extinction coefficients) and electrochemical stability of the complexes were noticeably different depending on size and metal ion center.