1357162-99-2Relevant academic research and scientific papers
Enantioselective allylation and crotylation of in situ generated β,γ-unsaturated aldehydes
McCubbin, J. Adam,Maddess, Matthew L.,Lautens, Mark
, p. 2857 - 2861 (2011)
β,γ-Unsaturated aldehydes generated in situ by treatment of 2-vinyloxiranes with a catalytic amount of Sc(OTf)3 are effectively trapped by ring-strained allyl- and crotylsilane reagents to afford bishomoallylic alcohols as single diastereomers in high enantiomeric excess. Georg Thieme Verlag Stuttgart · New York.
