1357170-68-3Relevant academic research and scientific papers
An efficient pyrrole synthesis via silaphenylmercuric triflate catalyzed cyclization of homopropargyl azides
Yamamoto, Hirofumi,Sasaki, Ikuo,Mitsutake, Mizuho,Karasudani, Ayumi,Imagawa, Hiroshi,Nishizawa, Mugio
, p. 2815 - 2818 (2012/01/05)
A mixture of phenylmercuric acetate and trifluoromethanesulfonic acid or silica gel supported phenylmercuric tri-fluoromethanesulfonate (silaphenyl mercuric triflate) efficiently catalyzed the formation of pyrroles from homopropargyl azide derivatives. The reactions proceed using 20 mol% of the heterogeneous catalyst with yields of isolated pyrroles ranging from 74% to 99%. Georg Thieme Verlag Stuttgart · New York.
