1357196-45-2Relevant articles and documents
Reaction of divinyl telluride with secondary phosphine chalcogenides
Gusarova,Chernysheva,Yas'ko,Klyba,Trofimov
experimental part, p. 2506 - 2509 (2012/04/10)
Divinyl telluride reacted with 2 equiv of diphenylphosphine sulfide in the presence of AIBN as radical initiator (63-68°C) to give the corresponding anti-Markovnikov adduct in 68% yield with high regioselectivity. Treatment of the addition product with aqueous hydrogen peroxide at room temperature afforded 71% of vinyldiphenylphosphine oxide. Radical addition of diphenylphosphine selenide to divinyl telluride (AIBN, 63-68°C) led to the formation of 1,1,3,3-tetraphenyldiphosphoxane 1,3-diselenide in 82% yield. Pleiades Publishing, Ltd., 2011.