1357375-06-4

Upstream product

• 105919-36-6 trans-4-(trifluoromethyl)cinnamoyl chloride 
• 94594-90-8 (2R)-bornane-10,2-sultam 
• 1357375-00-8 (-)-(2E)-1-[(3aS,6R,7aR)tetrahydro-8,8-dimethyl-2,2-dioxido-3H-3a,6-methano-2,1-benzisothiazol-1(4H)-yl]-3-[4-(trifluoromethyl)phenyl]prop-2-en-1-one 
• 925-90-6 ethylmagnesium bromide 

Relevant academic research and scientific papers

Grignard 1,4-Additions to para-Substituted (2R)-N-Cinnamoylbornane-10,2-sultam Derivatives: Revised Configuration for the N,OAc-Keteneacetal Formation in the Presence of Cu(I)

Using a19F-NMR analytical method, we have corrected and improved the linear correlation initially found between the diastereoselectivity observed during the EtMgBr conjugated addition to Michael acceptors of type 1, as a function of their σsub

Diastereoselective alkyl Grignard 1,4-additions to para-substituted (2R)-N-cinnamoylbornane-10,2-sultam derivatives: Influence of N-atom pyramidalization

Several typical 13C-NMR displacements (of C=O, C(α), C(β), and Cipso), as well as conformational or energy properties (S-N-C=O dihedral angle, ΔE syn/anti; HOMO/LUMO) could be correlated with the electronic parameters of p-substitute