135753-01-4Relevant academic research and scientific papers
Palladium-catalysed addition of tin-tin and tin-silicon bonds to allenes
Mitchell, Terence N.,Schneider, Ulrich
, p. 319 - 327 (2007/10/02)
Hexamethyl-, hexaethyl- and hexabutyl-ditin add to a variety of allenes in the presence of Pd(PPh3)4; the reaction is reversible.Trimethylsilyltrimethyl- and -tributyl-stannane also add under comparable conditions, the silyl moiety becoming attached to the central carbon atom of the allene skeleton; this reaction is, however, apparently not reversible.
