1357775-91-7

Basic information

• Product Name: C₂₆H₃₀N₄
• Synonyms: C₂₆H₃₀N₄
• CAS NO: 1357775-91-7
• Molecular Weight: 398.551
• Mol File: 1357775-91-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₂₆H₃₀N₄(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₆H₃₀N₄(1357775-91-7)
• EPA Substance Registry System: C₂₆H₃₀N₄(1357775-91-7)

Safety Data

• Hazardous Substances Data: 1357775-91-7(Hazardous Substances Data)

Upstream product

• 27956-35-0 2-(4-methylphenyl)malondialdehyde 
• 52568-28-2 2-(pyridin-2-yl)isopropyl amine 

Downstream Products

• 1357775-96-2 [CH₃C₆H₄(C₃H₂(N(C(CH₃)2C₅H₄N))2)]ZnI 

Relevant articles and documents

Synthesis and reactivity of an isolable cobalt(I) complex containing a β-diketiminate-based acyclic tetradentate ligand

A model for cobalamin was synthesized using a new monoanionic tetradentate nitrogen donor ligand; 2-(4- tolyl)-1,3-bis(2-isopropylpyridyl)propenediimine (Tol- BDI(2-pp)2H) (1), which utilizes isopropylpyridines as pendant arms on a β-diketiminate (BDI) backbone. During the synthesis of 1, the rearrangement product, Tol-BDI(2-pp)(4-pp)H (2) was observed. Metalation of 1 with zinc iodide and cobalt chloride yielded the corresponding Tol-BDI(2-pp)2ZnI (3) and Tol-BDI(2-pp)2CoCl (4) complexes. The redox properties of 4 in comparison to cobalamin were examined through electrochemical studies. Electrochemical and bulk reduction of complex 4 gave a diamagnetic cobalt(I) complex, Tol-BDI(2-pp)2Co (5). Reactivity of 5 toward C-X bonds was investigated using methyl iodide and 1-iodo-2-(trimethylsilyl)acetylene, yielding Tol-BDI(2-pp)2Co(CH 3)I and Tol-BDI(2-pp)2Co(C2Si(CH 3)3)I respectively. Synthesis and characterization details for these complexes, including the crystal structure of 3, are reported.