135778-06-2Relevant academic research and scientific papers
Highly unsaturated macrocyclic silahydrocarbons containing exocyclic phenyl groups
Yarosh,Zhilitskaya,Yarosh,Albanov,Voronkov
, p. 1552 - 1554 (2003)
A series of 12- and 18-membered macrocycloethynes and macrocyclosilethenesilethynes, containing peripheral methyl and phenyl groups was prepared by organomagnesium sysnthesis under conditions of high dilution. One of these compounds contains an endocyclic
Rigid rod molecules containing two Si(OMe)3 or SiMe(OMe)2 groups for hybrid materials synthesis
Cerveau, Geneviève,Chappellet, Sabrina,Corriu, Robert J.P.,Dabiens, Bertrand
, p. 92 - 99 (2007/10/03)
The synthesis of new bis(trimethoxysilyl) and bis(dimethoxymethylsilyl)arene compounds containing rigid organic groups such as stilbenyl, diphenylacetylene or diphenylbut-1,3-diyne is reported. The Heck type reaction constituted a convenient route to these compounds, since this coupling reaction appeared compatible with the presence of Si(OR)3 groups.
