135819-15-7

Basic information

• Product Name: (3S,4S)-4-(tert-Butyl-dimethyl-silanyloxy)-3-hydroxy-4-phenyl-thiobutyric acid S-ethyl ester
• CAS NO: 135819-15-7
• Molecular Weight: 354.586
• Mol File: 135819-15-7.mol

Chemical Properties

• CAS DataBase Reference: (3S,4S)-4-(tert-Butyl-dimethyl-silanyloxy)-3-hydroxy-4-phenyl-thiobutyric acid S-ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (3S,4S)-4-(tert-Butyl-dimethyl-silanyloxy)-3-hydroxy-4-phenyl-thiobutyric acid S-ethyl ester(135819-15-7)
• EPA Substance Registry System: (3S,4S)-4-(tert-Butyl-dimethyl-silanyloxy)-3-hydroxy-4-phenyl-thiobutyric acid S-ethyl ester(135819-15-7)

Safety Data

• Hazardous Substances Data: 135819-15-7(Hazardous Substances Data)

Upstream product

• 63584-41-8 1-ethylthio-1-(trimethylsiloxy)ethene 
• 133187-22-1 (2S)-2-(tert-butyldimethylsilyloxy)-2-phenylacetaldehyde 

Relevant articles and documents

The Chiral Catalyst Control. A Significant Role of a Chiral Catalyst in the Diastereoselective Aldol Reaction Using Chiral Aldehydes

The stereochemistry in the aldol reaction of a silyl enol ether with chiral aldehydes is almost completely controlled by the chiral catalyst regardless of the inherent diastereofacial preference of the chiral aldehydes.