135900-99-1

Basic information

• Product Name: 3-bromo-2-methyl-5-phenylthiophene 1,1-dioxide
• Synonyms: 3-bromo-2-methyl-5-phenylthiophene 1,1-dioxide
• CAS NO: 135900-99-1
• Molecular Formula: C₁₁H₉BrO₂S
• Molecular Weight: 285.15696
• Mol File: 135900-99-1.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 3-bromo-2-methyl-5-phenylthiophene 1,1-dioxide(CAS DataBase Reference)
• NIST Chemistry Reference: 3-bromo-2-methyl-5-phenylthiophene 1,1-dioxide(135900-99-1)
• EPA Substance Registry System: 3-bromo-2-methyl-5-phenylthiophene 1,1-dioxide(135900-99-1)

Safety Data

• Hazardous Substances Data: 135900-99-1(Hazardous Substances Data)

Upstream product

• 61285-25-4 3-bromo-2-methyl-5-phenylthiophene 

Relevant articles and documents

Further Examples of Tandem Dimerization Ring-Opening of Substituted 3-Bromothiophene 1,1-Dioxides. Preparation of Trisubstituted Benzenes. X-Ray Structure Determination of 3,5-Dibromo-7,7a-dimethyl-2,4-diphenyl-cis-3a,7a-dihydrobenzothiophene 1,1-Dioxide

Stirring 3-bromo-2-methylthiophene 1,1-dioxide, 3-bromo-2-butylthiophene 1,1-dioxide and 3-bromo-2-phenylthiophene 1,1-dioxide at room temperature with basic alumina in pentane-dichloromethane solution led to dihydrobenzothiophene 1,1-dioxides.Refluxing of the same reaction mixtures led to the ring-opening products, the trisubstituted benzenes.Refluxing of 3-bromo-5-methyl-2-phenylthiophene 1,1-dioxide in decalin afforded the 3,5-dibromo-7,7a-dimethyl-2,4-diphenyl-cis-3a,7a-dihydrobenzothiophene 1,1-dioxide.The structure was established by X-ray crystallography.