135957-91-4

Upstream product

• 137-18-8 2,5-Dimethyl-1,4-benzoquinone 
• 114934-91-7 4-hydroxy-4-(perfluorooctyl)-2,5-cyclohexadien-1-one 
• 134284-62-1 4-Hydroxy-2,5-dimethyl-4-perfluorooctyl-2,5-cyclohexadien-1-one 

Relevant academic research and scientific papers

Perfluoroalkyl migration in the rearrangement of 4-perfluoroalkyl-4-quinols

Heating a DMSO solution of 4-(perfluoro-n-alkyl)-4-hydroxy-2,5-cyclohexadien-1-one (4-perfluoroalkyl-4-quinols) in the presence of a catalytic amount of base brought about 1,2-migration of the perfluoroalkyl group to give 2-(perfluoro-n-alkyl)hydroquinone

1,2-Migration of Perfluoroalkyl Groups in Anionotropic Rearrangement. The Acyloin Rearrangement of 4-Perfluoroalkyl-4-quinols

Treatment of 4-perfluoroalkyl-4-quinols with a catalytic amount of potassium t-butoxide gave 2-(perfluoroalkyl)hydroquinones or 5-perfluoroalkyl-2-cyclohexene-1,4-diones in good to moderate yields depending upon the substitution pattern of the quinols.Similarly, 2-hydroxy-3-methyl-2-perfluorooctyl-1-propyl-3-pyrrolin-5-one underwent the base-induced rearrangement to afford a perfluoroalkylated succinimide derivative.