13597-13-2

Basic information

• Product Name: 1,4-bis(phenylselanyl)but-2-yne
• Synonyms: 1,4-bis(phenylselanyl)but-2-yne
• CAS NO: 13597-13-2
• Molecular Weight: 364.207
• Mol File: 13597-13-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,4-bis(phenylselanyl)but-2-yne(CAS DataBase Reference)
• NIST Chemistry Reference: 1,4-bis(phenylselanyl)but-2-yne(13597-13-2)
• EPA Substance Registry System: 1,4-bis(phenylselanyl)but-2-yne(13597-13-2)

Safety Data

• Hazardous Substances Data: 13597-13-2(Hazardous Substances Data)

Upstream product

• 645-96-5 Benzeneselenol 
• 821-10-3 1,4-Dichloro-2-butyne 
• 40973-72-6 potassium phenyl selenide 
• 1666-13-3 diphenyl diselenide 

Relevant articles and documents

Chalcogenation of 1,4-dichlorobut-2-yne with organic dichalcogenides in the system hydrazine hydrate–KOH

A reaction of organic dichalcogenides R2Y2 (R = Ph, Bn, Pr; Y = S, Se) with 1,4-dichlorobut-2-yne in the system hydrazine hydrate–KOH leads to four principal products: 1,4-bis(organylchalcogenyl)but-2-ynes, 1-organylchalcogenylbut-1-en-3-ynes, 4-organylchalcogenylbut-1-en-3-ynes, and 3(5)-methylpyrazole. The selectivity of the formation of individual products is determined by the ratio of the substrates used and the reaction temperature. A plausible mechanism of chalcogenation considered in the work agrees with the effect of the nature of chalcogene atoms and organic substituents R on stability of intermediates and products. The stabilization of carbanions by α chalcogene-containing groups corresponds to the following order: PhS > PhSe > BnS > BnSe > PrS.