1359950-53-0

Upstream product

• 71703-29-2 2-benzyl-3-hydroxy-5,5-dimethyl-cyclohex-2-enone 
• 1359950-48-3 C₂₃H₂₆OSi 
• 1359950-58-5 C₁₉H₂₆O₂ 
• 1330776-66-3 2-[1,3-bis(4-chlorophenyl)-3-oxopropyl]-3-hydroxy-5,5-dimethylcyclohex-2-enone 
• 1330776-64-1 3-hydroxy-5,5-dimethyl-2-[1-(4-nitrophenyl)-3-oxo-3-phenylpropyl]cyclohex-2-enone 
• 638211-09-3 2-[1-(4-chlorophenyl)-3-oxo-3-phenylpropyl]-3-hydroxy-5,5-dimethylcyclohex-2-enone 
• 1330776-62-9 3-hydroxy-2-[1-(4-methoxyphenyl)-3-oxo-3-phenylpropyl]-5,5-dimethylcyclohex-2-enone 
• 1330776-61-8 3-hydroxy-5,5-dimethyl-2-(3-oxo-3-phenyl-1-p-tolylpropyl)cyclohex-2-enone 

Relevant academic research and scientific papers

Synthesis of Acylsilanes via Catalytic Dedithioacetalization of 2-Silylated 1,3-Dithianes with 30% Hydrogen Peroxide

Acylsilanes were obtained efficiently from dedithioacetalization of 2-silylated 1,3-dithianes using 30% hydrogen peroxide catalyzed by iron(III) acetylacetonate-sodium iodide. The use of niobium(V) chloride as a catalyst instead of iron(III) acetylacetonate was also effective, except in synthesizing some acyltrimethylsilanes.

Metal-free relay oxidation: Valuable synthesis of acylsilane and ketones under aerobic oxidation

In this letter, an example of interesting metal-free relay air oxidation of -hydroxysilanes, promoted by the hydroperoxidated carbonyl compounds derived from the Michael reaction of 5,5-dimethylcyclohexane-1,3-dione and chalcone, is reported. A series of aromatic acylsilanes with TBDPS were obtained in promising isolated yields. In addition, as an extension of the relay oxidation under aerobic conditions, this catalyst-free relay oxidation induced by diketone can be applied to the oxidation of general aromatic alcohols (up to 75% yield). Georg Thieme Verlag Stuttgart · New York.