136000-24-3Relevant academic research and scientific papers
New approach to the synthesis of trifluoromethylvinyl sulfides
Muzalevskiy,Shastin,Balenkova,Nenajdenko
, p. 1526 - 1533 (2008/09/18)
Nucleophilic substitution reaction of halogen atom in β-chloro-and β-bromo-β-trifluoromethylstyrenes by thiolates was studied. Stereo-and regioselectivity of the reaction with respect to the electronic and sterical properties of substituents in the aromat
Synthesis of trifluoromethylalkenes and alkynes. Trifluoromethyl captodative olefins
Laurent,Le Drean,Selmi
, p. 3071 - 3074 (2007/10/02)
β-ethylthio-β-trifluoromethylketones 3 and aldehydes 4 are easily prepared from β-chloroolefines 5 and 6. Trifluoromethylalkynes 7 and captodative alkenes 8 are obtained by reaction of KOH on aldehydes 6 or 4.
