1360075-82-6Relevant articles and documents
Highly fluorinated aryl-substituted tris(indazolyl)borate thallium complexes: Diverse regiochemistry at the B-N bond
Ojo, Wilfried-Solo,Jacob, Kane,Despagnet-Ayoub, Emmanuelle,Munoz, Bianca K.,Gonell, Sergio,Vendier, Laure,Nguyen, Viet-Hoang,Etienne, Michel
, p. 2893 - 2901 (2012)
The synthesis and characterization (mainly by 19F NMR and X-ray diffraction) of highly fluorinated aryl-4,5,6,7-tetrafluoroindazoles and their corresponding thallium hydrotris(indazolyl)borate complexes are reported [aryl = phenyl, pentafluorophenyl, 3,5-dimethylphenyl, 3,5-bis(trifluoromethyl)phenyl]. Thanks to N-H???N hydrogen bonds, the indazoles crystallize as dimers that pack differently depending on the nature of the aryl group. The thallium hydrotris(indazolyl)borate complexes Tl[Fn-Tp4Bo,3aryl] resulting from the reaction of aryl-4,5,6,7-tetrafluoroindazoles [aryl = phenyl, 3,5-dimethylphenyl, 3,5-bis(trifluoromethyl)phenyl] with thallium borohydride adopt overall C3v symmetry with the indazolyl groups bound to boron via their N-1 nitrogen in a conventional manner. When the perfluorinated pentaphenyl-4,5,6,7-tetrafluoroindazole is reacted with thallium borohydride, a single regioisomer of Cs symmetry having one indazolyl ring bound to boron via its N-2 nitrogen, TlHB(3-pentafluorophenyl-4,5,6,7-tetrafluoroindazol- 1-yl)2(3-pentafluorophenyl-4,5,6,7-tetrafluoroindazol-2-yl) Tl[F27-Tp(4Bo,3C6F5)*], is obtained for the first time. Surprisingly, the perfluorinated dihydrobis(indazolyl)borate complex Tl[F 18-Bp3Bo,3C6F5], an intermediate on the way to the hydrotris(indazolyl)borate complex, has Cs symmetry with two indazolyl rings bound to boron via N-2. The distortion of the coordination sphere around Tl and the arrangement of the complexes in the crystal are discussed.
