1360140-05-1

Basic information

• Product Name: [HN(CH₂CH₂NHPiPr₂)2Ni(o-C₆H₄F)]Cl
• CAS NO: 1360140-05-1
• Molecular Weight: 524.692
• Mol File: 1360140-05-1.mol

Chemical Properties

• CAS DataBase Reference: [HN(CH₂CH₂NHPiPr₂)2Ni(o-C₆H₄F)]Cl(CAS DataBase Reference)
• NIST Chemistry Reference: [HN(CH₂CH₂NHPiPr₂)2Ni(o-C₆H₄F)]Cl(1360140-05-1)
• EPA Substance Registry System: [HN(CH₂CH₂NHPiPr₂)2Ni(o-C₆H₄F)]Cl(1360140-05-1)

Safety Data

• Hazardous Substances Data: 1360140-05-1(Hazardous Substances Data)

Upstream product

• 1295-35-8 bis(1,5-cyclooctadiene)nickel ⁽⁰⁾ 
• 348-51-6 1-chloro-2-fluorobenzene 
• 1360139-99-6 NH((CH₂)2NHPiPr₂)2 

Relevant articles and documents

Oxidative addition reactions of bis-aminophosphine and bis-phosphinite nickel(0) pincer complexes

The tridentate ligands S(CH2CH2NHPiPr 2)2 and S(CH2CH2OPiPr 2)2 undergo C-S oxidative addition to give (SCH 2CH2EPiPr2)Ni(CH2CH 2EPiPr2) (E = NH (2), O (4)). The corresponding reaction of the aminophosphine ligand HN(CH2CH2NHPiPr 2)2 is reversible, affording access to a transient Ni(0) synthon that undergoes oxidative addition with HCl, MeI, or o-ClC 6H4F to give the Ni(II) complexes [HN(CH 2CH2NHPiPr2)2NiR]X (R = H, X = Cl (7), PF6 (8); R = Me, X = I (9); R = o-C6H4F, X = Cl (10)). These observations are supported via computations.