136015-82-2

Upstream product

• 16029-98-4 trimethylsilyl iodide 
• 7486-35-3 tri-n-butyl(vinyl)tin 
• 536-74-3 phenylacetylene 
• 1428671-53-7 (Z)-trimethyl[4-(phenylselanyl)-2-(tributylstannyl)but-1-enyl]silane 
• 591-50-4 iodobenzene 
• 1428671-54-8 (Z)-trimethyl[2-(tributylstannyl)buta-1,3-dienyl]silane 
• 1428671-63-9 (Z)-trimethyl[2-phenyl-4-(phenylselanyl)but-1-enyl]silane 
• 18107-18-1 diazomethyl-trimethyl-silane 

Relevant academic research and scientific papers

A stereoselective approach to (Z)-1-Silyl-2-aryl-1,3-dienes from 4-(Phenylselanyl)but-1-yne via palladium-catalyzed silylstannylation and selenoxide elimination

The palladium-catalyzed silylstannylation of 4-(phenylselanyl)but-1-yne proceeded regio- and stereoselectively, followed by selenoxide elimination via oxidation to give (Z)-1-(trimethylsilyl)-2-(tributylstannyl)buta-1,3-diene in good yield. This conjugated diene underwent the Stille coupling reaction with various aryl iodides in the presence of Pd(PPhto afford (Z)-2-aryl-1- (trimethylsilyl)buta-1,3-dienes with high stereoselectivity. Reversing the order of selenoxide elimination and Stille coupling reaction in the synthetic procedure also resulted in good yields of (Z)-2-aryl-1-(trimethylsilyl)buta-1,3- dienes. Georg Thieme Verlag Stuttgart - New York.

Ruthenium-catalyzed synthesis of functional conjugated dienes via addition of two carbene units to alkynes

The reaction of a variety of alkynes with N2CHSiMe3, in the presence of Cp*RuCl(cod) as the catalyst precursor, leads to the general formation of functional conjugated dienes. This selective formation results from the ruthenium-catal