136052-67-0Relevant academic research and scientific papers
THE PECULIAR α-AMIDOALKYLATION OF VINYLTRIMETHYLSILANE
Ebeling, Sabine,Matthies, Dieter,McCarthy, Daniel
, p. 265 - 273 (2007/10/02)
α-Amidoalkylation of allyltrimethylsilane with methyl-2-chloro-2-(p-chlorobenzoylamino)-ethanoate 1 gave in the presence of Lewis acid racemic methyl-2-(p-chlorobenzoylamino)-4-pentenoate 2.Under the same conditions, vinyltrimethylsilane afforded (+/-)-trans-2-(p-chlorophenyl)-5,6-dihydro-4-methoxycarbonyl-6-trimethylsilyl-4H-1,3-oxazine 4 as the major, by n.m.r. data and X-ray crystallography established product.
