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Macrobicyclic Endoreceptors: Synthesis, Crystal Structure, and Inclusion of Organic Guests
Lueer, Ingo,Rissanen, Kari,Voegtle, Fritz
, p. 1873 - 1880 (2007/10/02)
The macrobicyclic ligand 2 is synthesized in a one-step cyclization procedure.According to an X-ray structure analysis three dichloromethane guest molecules are included inside the cavity, whereas water and methanol are found outside the cavity.The rigid endo preorganization of the nitrogen donors allows the complexation of three 2,9-disubstituted 1,10-phenanthrolines inside the cavity. Key Words: Complex formation / Endoreceptors / Macrobicyclic ligands / Phenanthroline derivatives / Supramolecular chemistry
