1360593-33-4Relevant academic research and scientific papers
Diastereoselective Synthesis of Dibenzo[b,d]azepines by Pd(II)-Catalyzed [5 + 2] Annulation of o-Arylanilines with Dienes
Bai, Lu,Wang, Yan,Ge, Yicong,Liu, Jingjing,Luan, Xinjun
supporting information, p. 1734 - 1737 (2017/04/11)
An efficient method for the construction of dibenzo[b,d]azepines containing two distinct stereogenic elements in a highly diastereoselective fashion is described. The key of the [5 + 2] reaction is to form a π-allylpalladium species through sequential C-H
Palladium-catalyzed oxidative insertion of carbon monoxide to N -sulfonyl-2-aminobiaryls through C-H bond activation: Access to bioactive phenanthridinone derivatives in one pot
Rajeshkumar, Venkatachalam,Lee, Tai-Hua,Chuang, Shih-Ching
, p. 1468 - 1471 (2013/06/26)
Palladium-catalyzed oxidative carbonylation of N-sulfonyl-2-aminobiaryls through C-H bond activation and C-C, C-N bond formation under TFA-free and milder conditions has been developed. The reaction tolerates a variety of substrates and provides biologically important phenanthridinone derivatives in yields up to 94%.
Palladium-catalyzed and hybrid acids-assisted synthesis of [60]fulleroazepines in one pot under mild conditions: Annulation of N-sulfonyl-2-aminobiaryls with [60]fullerene through sequential C-H bond activation, C-C and C-N bond formation
Rajeshkumar, Venkatachalam,Chan, Fu-Wei,Chuang, Shih-Ching
supporting information, p. 2473 - 2483,11 (2020/08/31)
An extraordinarily efficient hybrid acids-assisted, palladium-catalyzed and chelating-group-assisted C-H bond activation of N-sulfonyl-2-aminobiaryls and their annulations with [60]fullerene via sequential C-C and C-N bond formation at room temperature to
