1360618-97-8Relevant articles and documents
The total synthesis and structural revision of stagonolide D
Vadhadiya, Paresh M.,Puranik, Vedavati G.,Ramana
, p. 2169 - 2175 (2012)
The total synthesis of the putative structure of stagonolide D has been completed. The relative and absolute configuration of stagonolide D was established by synthesizing its optical antipode. The adopted strategy involves the construction of the central macrolide employing ring-closing metathesis (RCM), followed by selective protecting group manipulations and a final concomitant -OTBS deprotection and displacement of an -OMs placed next to it, resulting in the formation of the epoxide ring.