136063-27-9

Upstream product

• 154137-44-7 methyl 2-ethyl-3-<2-(2',6',6'-trimethyl-5'-oxocyclohexyl)ethyl>benzoate 
• 136063-26-8 methyl 2-ethyl-3-<2-(2',6',6'-trimethyl-3'-oxocyclohex-1-enyl)vinyl>benzoate 
• 136063-25-7 3-<2-<3-(4,4-dimethyl-4,5-dihydrooxazol-2-yl)-2-ethylphenyl>vinyl>-2,4,4-trimethylcyclohex-2-enone 
• 563-80-4 3-methyl-butan-2-one 
• 75934-02-0 2-(3-allyl-2-methoxyphenyl)-4,4-dimethyl-4,5-dihydrooxazole 
• 136063-21-3 2-(3-allyl-2-ethylphenyl)-4,4-dimethyl-4,5-dihydrooxazole 
• 136063-22-4 2-[2-Ethyl-3-((E)-propenyl)-phenyl]-4,4-dimethyl-4,5-dihydro-oxazole 
• 136063-23-5 3-(4,4-dimethyl-4,5-dihydrooxazol-2-yl)-2-ethylbenzaldehyde 
• 136063-24-6 1-<3-(4,4-dimethyl-4,5-dihydrooxazol-2-yl)-2-ethylphenyl>-4-methylpent-1-en-3-one 

Downstream Products

• 69940-49-4 (+/-)-veadeirol 
• 69903-86-2 (+/-)-veadeiroic acid 

Relevant academic research and scientific papers

Stereoselective Synthesis of (+/-)-Veadeiroic Acid and (+/-)-Veadeirol by Cyclisation of a 2-(2-Arylethyl)-1,3,3-trimethylcyclohexyl Cation: Mechanism and Stereochemistry of Related Cycloalkylation Reactions

(+/-)-Veadeiroic acid 1 and (+/-)-veadeirol 2, two new cleistanthoid diterpenes, have been synthesized by stereoselective cyclization of the carbocation 5 generated from the cyclohexanol 26.The latter is prepared from 2-ethyl-3-formylbenzoic acid (with CO

A stereoselective synthesis of (±)-veadeiroic acid and (±)-veadeirol - Two novel diterpenes with cleistanthane skeleton

A stereoselective synthesis of (±)-veadeiroic acid (X) and (±)-veadeirol (XI), diterpenes with cleistanthane skeleton is described. The key step in the synthesis is a stereoselective ring-closure of a substituted arylethyltrimethylcyclohexanol (VIII).