136068-14-9Relevant academic research and scientific papers
Tin-free radical carbonylation: Thiol ester synthesis using alkyl allyl sulfone precursors, phenyl benzenethiosulfonate, and CO
Kim, Sangmo,Kim, Sunggak,Otsuka, Noboru,Ryu, Ilhyong
, p. 6183 - 6186 (2007/10/03)
(Chemical Equation Presented) Remove contents from tin ... Thiol esters have been successfully synthesized through tin-free radical carbonylation (see scheme; V-40 = initiator). This approach can be further extended to sequential radical reactions involving cyclization, carbonylation, and trapping of acyl radicals by phenyl benzenethiosulfonate.
Generation of β-Carbonyl Radicals from Cyclopropanol Derivatives by the Oxidation with Manganese(III) 2-Pyridinecarboxylate and Their Reactions with Electron-Rich and -Deficient Olefins
Iwasawa, Nobuharu,Hayakawa, Satoshi,Funahashi, Masahiro,Isobe, Koichi,Narasaka, Koichi
, p. 819 - 827 (2007/10/02)
Various β-carbonyl radicals are generated oxidatively from cyclopropanol derivatives by the use of manganese(III) 2-pyridinecarboxylate (Mn(pic)3).These β-carbonyl radicals react with electron-rich olefins such as conjugated silyl enol ethers, a ketene th
Generation of β-Keto Radicals from Cyclopropanol Derivatives by the Use of Manganese(III) 2-Pyridinecarboxylate as an Oxidant and Their Reactions with Olefins
Iwasawa, Nobuharu,Hayakawa, Satoshi,Isobe, Koichi,Narasaka, Koichi
, p. 1193 - 1196 (2007/10/02)
Various β-keto radicals are generated from cyclopropanol derivates such as 1- or 2-substituted cyclopropanols and a cyclopropanone hemiacetal by the use of manganese(III) 2-pyridinecarboxylate, and their reactions with electron-rich olefins give cross-addition products in good yields.
