1360733-62-5Relevant academic research and scientific papers
Biotransformations of racemic 2,3-allenenitriles in biphasic systems: Synthesis and transformations of enantioenriched axially chiral 2,3-allenoic acids and their derivatives
Ao, Yu-Fei,Wang, De-Xian,Zhao, Liang,Wang, Mei-Xiang
, p. 3103 - 3110 (2014/05/06)
Catalyzed by Rhodococcus erythropolis AJ270 whole cells in an aqueous phosphate buffer-n-hexane biphasic system, racemic axially chiral 2,3-allenenitriles underwent hydrolysis to afford enantioenriched (aR)-2,3-allenamides and (aS)-2,3-allenoic acids with
N -heterocyclic carbene-catalyzed internal redox reaction of alkynals: An efficient synthesis of allenoates
Zhao, Yu-Ming,Tam, Yik,Wang, Yu-Jie,Li, Zigang,Sun, Jianwei
supporting information; experimental part, p. 1398 - 1401 (2012/06/01)
An efficient N-heterocyclic carbene (NHC)-catalyzed internal redox reaction of alkynals that bear a γ leaving group has been developed. This process provides a new access to a range of allenoates in good yields. Preliminary results demonstrate that the en
