136086-95-8Relevant academic research and scientific papers
Catalytic asymmetric aldol-type reaction using a chiral tin(II) Lewis acid
Kobayashi,Uchiro,Shiina,Mukaiyama
, p. 1761 - 1772 (2007/10/02)
Highly diastereo- and enantioselective aldol-type reactions of a silyl enol ether with aldehydes including aromatic, aliphatic, and α,β-unsaturated ones are performed in propionitrile (solvent) by the use of a catalytic amount of chiral tin(II) Lewis acid
An Efficient Asymmetric Aldol Reaction Promoted by a Chiral Tin(II) Lewis Acid Consisting of Tin(II) Triflate, (R)-2-tetrahydrothiophene and Tin(IV) Compuond
Mukaiyama, Teruaki,Asanuma, Hajime,Hachiya, Iwao,Harada, Tsunehiro,Kobayashi, Shu
, p. 1209 - 1212 (2007/10/02)
The title chiral Lewis acid is succesfully employed in the enantioselective aldol reactions of silyl enol ether of S-ethyl propanethioate with achiral aldehydes to afford the corresponding aldol-type adducts in a highly stereoselective manner.
