1360864-33-0Relevant articles and documents
A chiral phenoxyamine magnesium catalyst for the enantioselective hydroamination/cyclization of aminoalkenes and intermolecular hydroamination of vinyl arenes
Zhang, Xiaoming,Emge, Thomas J.,Hultzsch, Kai C.
, p. 394 - 398 (2012)
If Grignard had only known! A chiral magnesium complex catalyzes the intramolecular hydroamination/cyclization of aminoalkenes with high efficiency at temperatures as low as -20 °C and enantioselectivities as high as 93 %ee. The high activity of this system also allows the catalytic intermolecular anti-Markovnikov addition of pyrrolidine and benzylamine to vinyl arenes. Copyright