1360868-23-0

Basic information

• Product Name: (+/-)-(6,6'-dimethoxybiphenyl-2,2'-diyl)bis{bis[2,6-bis(trifluoromethyl)-4-pyridyl]phosphine}
• CAS NO: 1360868-23-0
• Molecular Weight: 1130.56
• Mol File: 1360868-23-0.mol

Chemical Properties

• CAS DataBase Reference: (+/-)-(6,6'-dimethoxybiphenyl-2,2'-diyl)bis{bis[2,6-bis(trifluoromethyl)-4-pyridyl]phosphine}(CAS DataBase Reference)
• NIST Chemistry Reference: (+/-)-(6,6'-dimethoxybiphenyl-2,2'-diyl)bis{bis[2,6-bis(trifluoromethyl)-4-pyridyl]phosphine}(1360868-23-0)
• EPA Substance Registry System: (+/-)-(6,6'-dimethoxybiphenyl-2,2'-diyl)bis{bis[2,6-bis(trifluoromethyl)-4-pyridyl]phosphine}(1360868-23-0)

Safety Data

• Hazardous Substances Data: 1360868-23-0(Hazardous Substances Data)

Upstream product

• 43150-55-6 2,6-bis(trifluoromethyl)-4-hydroxypyridine 
• 425639-29-8 2,6-bis(trifluoromethyl)-2,6-dihydroxytetrahydropyran-4-one 
• 134914-92-4 4-bromo-2,6-bis(trifluoromethyl)pyridine 
• 1160008-29-6 (+/-)-(6,6'-dimethoxybiphenyl-2,2'-diyl)bis(dichlorophosphine) 

Relevant articles and documents

Synthesis and application of 2,6-bis(trifluoromethyl)-4-pyridyl phosphanes: The most electron-poor aryl phosphanes with moderate bulkiness

The poor will be rich: BFPy phosphanes (see scheme) mimic the electronic and steric characters of P(C6F5)3 and PPh 3, respectively. These novel ligands showed a large ligand acceleration effect on Stille coupling, the Rh-catalyzed 1,2-addition of aryl boronic acid to unactivated ketones and the asymmetric arylation of N-tosylimine using phenylboronic acid. Copyright