136087-19-9Relevant academic research and scientific papers
Fluorination reactions at C-4 of methyl 2-O-benzyl-3,6-dideoxyhexopyranosides with diethylaminosulfur trifluoride (DAST) and with tris(dimethylamino)sulfonium difluorotrimethylsilicate (TASF)
Mori,Morishima
, p. 1088 - 1090 (2007/10/02)
Fluorination at C-4 of methyl 2-O-benzyl-3,6-dideoxy-α-D-ribo- and α-D-arabino-hexopyranosides (1 and 5) using diethylaminosulfur trifluoride (DAST) proceeded with exclusive retention of configuration. But treating the triflates of 1 and 5 with tris(dimethylamino)sulfonium difluorotrimethylsilicate (TASF) afforded mostly the configurationally inverted fluorides.
