1360895-89-1Relevant academic research and scientific papers
Synthesis of multi-substituted vinylsilanes via copper(i)-catalyzed hydrosilylation reactions of allenes and propiolate derivatives with silylboronates
Xu, Yun-He,Wu, Liu-Hai,Wang, Jun,Loh, Teck-Peng
supporting information, p. 7195 - 7197 (2014/07/07)
An efficient and general copper(i)-catalyzed method for the synthesis of multi-substituted vinylsilanes is reported. Multi-substituted allenes with electron-withdrawing groups and propiolate derivatives reacted well with (dimethylphenylsilyl)boronic acid
Activation of Si-Si bonds for copper(I)-catalyzed conjugate silylation
Iannazzo, Laura,Molander, Gary A.
, p. 4923 - 4926,4 (2020/08/24)
Several alkyl- and vinylsilanes were prepared through the copper(I)-catalyzed conjugate silylation of α,β-unsaturated compounds. Optimal reaction conditions were first investigated to realize the conjugate addition of a nucleophilic silicon species to poo
Palladium-catalyzed regio- and stereoselective hydrosilylation of electron-deficient alkynes
Sumida, Yuto,Kato, Tomoe,Yoshida, Suguru,Hosoya, Takamitsu
supporting information; experimental part, p. 1552 - 1555 (2012/06/15)
Highly regio- and stereoselective hydrosilylation applicable to a broad range of electron-deficient alkynes has been established using palladium catalysis. The synthetic utility of the method has been demonstrated by further transformations of α-silylalke
