1360896-45-2Relevant articles and documents
Palladium-catalyzed regio- and stereoselective hydrosilylation of electron-deficient alkynes
Sumida, Yuto,Kato, Tomoe,Yoshida, Suguru,Hosoya, Takamitsu
supporting information; experimental part, p. 1552 - 1555 (2012/06/15)
Highly regio- and stereoselective hydrosilylation applicable to a broad range of electron-deficient alkynes has been established using palladium catalysis. The synthetic utility of the method has been demonstrated by further transformations of α-silylalke
Activation of Si-Si bonds for copper(I)-catalyzed conjugate silylation
Iannazzo, Laura,Molander, Gary A.
, p. 4923 - 4926,4 (2020/08/24)
Several alkyl- and vinylsilanes were prepared through the copper(I)-catalyzed conjugate silylation of α,β-unsaturated compounds. Optimal reaction conditions were first investigated to realize the conjugate addition of a nucleophilic silicon species to poo