1361041-82-8Relevant academic research and scientific papers
Enzyme-catalyzed asymmetric construction of chiral tertiary alcohols via aldol reaction using proteinase
Li, Rui,Li, Zhi-Lin,Zhou, Hai-Yan,He, Yan-Hong,Guan, Zhi
, p. 90 - 98 (2016)
A new enzyme-catalyzed asymmetric construction of chiral tertiary alcohols via asymmetric aldol reactions between β,γ-unsaturated α-keto esters and ketones was reported. Proteinase from Aspergillus melleus (AMP) was used as a sustainable biocatalyst. The
An achiral-acid-induced switch in the enantioselectivity of a chiral cis-diamine-based organocatalyst for asymmetric aldol and Mannich reactions
Moteki, Shin A.,Han, Jianwei,Arimitsu, Satoru,Akakura, Matsujiro,Nakayama, Keiji,Maruoka, Keiji
supporting information; experimental part, p. 1187 - 1190 (2012/03/08)
Pick and choose: The asymmetric synthesis of two different enantiomeric products has been achieved through the use of a single organocatalyst with or without achiral organic acid additives (see scheme). These additives may assist in altering the substrate
