1361049-67-3

Upstream product

• 1361049-60-6 methyl (3R,5R)-5-(tert-butyldimethylsilyloxy)-3-hydroxy-6-heptenoate 
• 1361049-71-9 C₁₆H₂₆O₆Si 
• 1361049-72-0 (5R,2'R)-3-(benzyloxy)-5-[2'-(tert-butyldimethylsilyloxy)but-3'-enyl]-4-(methoxycarbonyl)furan-2(5H)-one 
• 1361049-61-7 C₂₂H₃₀O₆Si 
• 1361049-73-1 (5R,2'R)-3-(benzyloxy)-5-[2'-(tert-butyldimethylsilyloxy)but-3'-enyl]-4-(hydroxymethyl)furan-2(5H)-one 
• 1361049-62-8 (5R,2'R)-3-(benzyloxy)-5-[2'-(tert-butyldimethylsilyloxy)but-3'-enyl]-4-(benzoyloxymethyl)furan-2(5H)-one 
• 1361049-63-9 (1R,4R,6R,7R,9R)-9-benzoyloxymethyl-7-(tert-butyldimethylsilyloxy)-4-hydroxy-2-oxa-tricyclo[4.2.1.0(4,9)]nonan-3-one 
• 1361049-65-1 C₅₃H₆₃ClO₁₂Si 
• 917-54-4 methyllithium 
• 1361049-70-8 methyl (5R)-5-hydroxy-3-oxo-6-heptenoate 
• 521315-88-8 methyl (3R,5R)-3,5-dihydroxy-6-heptenoate 

Downstream Products

• 1361049-83-3 C₄₃H₅₈O₁₀Si 
• 1361049-66-2 C₄₃H₅₆O₉Si 
• 1361049-76-4 C₅₀H₆₀O₁₀Si 
• 1361049-68-4 C₄₄H₄₄O₁₀ 
• 1361049-59-3 (+)-lactiflorin 
• 1361049-69-5 C₂₉H₃₂O₁₃ 

Relevant academic research and scientific papers

Total synthesis of (+)-lactiflorin by an intramolecular [2+2] photocycloaddition

Enlightning synthesis: A light-induced intramolecular [2+2] photocycloaddition reaction (1→2) was the key step in the stereoselective synthesis of (+)-lactiflorin (3) and its triacetate. By comparison with reported analytical data, it was possible to unambiguously elucidate the structure of this natural product, to which three different structures had been previously assigned. Copyright