1361146-95-3

Upstream product

• 1572-71-0 (E)-2-methylpenta-2,4-dien-1-ol 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 75088-96-9 (2E)-ethyl 2-methylpenta-2,4-dienoate 
• 122057-55-0 2-methyl-2,4-pentadienoic acid methyl ester 

Downstream Products

• 663949-46-0 C₂₅H₃₄O₃Si 
• 1361146-56-6 (S,E)-5-((tert-butyldiphenylsilyl)oxy)-4-methylpent-3-ene-1,2-diol 
• 1422278-52-1 (1R,2R,3S,4S)-2-(((tert-butyldiphenylsilyl)oxy)methyl)-2-methyl-3-vinylcyclohexane-1,4-diol 
• 1422278-51-0 (1S,2S,3R,4R)-2-(((tert-butyldiphenylsilyl)oxy)methyl)-2-methyl-3-vinylcyclohexane-1,4-diol 

Relevant academic research and scientific papers

Synthesis of Two Key Fragments of the Complex Polyhalogenated Marine Meroterpenoid Azamerone

A concise route toward two advanced fragments in the context of the total synthesis of the unique natural product azamerone is reported. Key synthetic features include the enantioselective synthesis of an epoxysilane and its Lewis-acid-induced cyclization and the installation of the pyridazine ring via a formylation/condensation sequence. This route provides strategic insights into the chemistry of phthalazinediols, facilitating synthetic approaches toward this class of natural products.

Catalytic enantioselective 1,2-diboration of 1,3-dienes: Versatile reagents for stereoselective allylation

More with boron: The development of catalytic enantioselective 1,2-diboration of 1,3-dienes enables a new strategy for enantioselective carbonyl allylation reactions (see scheme). These reactions occur with outstanding levels of stereoselection and can be applied to both monosubstituted and 1,1-disubstituted dienes. The carbonyl allylation reactions provide enantiomerically enriched functionalized homoallylic alcohol products. Copyright