136123-56-3Relevant academic research and scientific papers
Direct Transformations of Ketones to γ-Unsaturated Thiols via [2,3]-Sigmatropic Rearrangement of Allyl Sulfinyl Carbanions: A Combined Experimental and Computational Study
Fokin, Andrey A.,Kushko, Andrey O.,Kirij, Anton V.,Yurchenko, Alexander G.,Schleyer, Paul V. R.
, p. 2984 - 2995 (2000)
The reaction of a series of ketones with dimsylsodium in dimethyl sulfoxide resulting in the formation of γ-unsaturated thiols was studied experimentally. [2,3]-Sigmatropic rearrangements of β-unsaturated sulfinyl carbanions are involved at the key step o
