1361257-64-8

Basic information

• Product Name: trans-1-bromo-1,2-difluorohexene
• Synonyms: trans-1-bromo-1,2-difluorohexene
• CAS NO: 1361257-64-8
• Molecular Weight: 199.038
• Mol File: 1361257-64-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: trans-1-bromo-1,2-difluorohexene(CAS DataBase Reference)
• NIST Chemistry Reference: trans-1-bromo-1,2-difluorohexene(1361257-64-8)
• EPA Substance Registry System: trans-1-bromo-1,2-difluorohexene(1361257-64-8)

Safety Data

• Hazardous Substances Data: 1361257-64-8(Hazardous Substances Data)

Upstream product

• 38932-80-8 tetra-N-butylammonium tribromide 

Relevant articles and documents

Reactions of perfluorinated alkenyl-, alkynyl-, alkyltrifluoroborates, and selected hydrocarbon analogues with the halogenating agents Hal2 (Hal = F, Cl, Br), "brF" (BrF3-Br2 1:1), and ICl

Reactions of [Bu4N][RBF3] [R = CnF 2n+1CF=CF (cis, trans), CF2=CF, CF2=C(CF 3), trans-C4H9CF=CF, trans-C6H 5CF=CF, C4H9CH=CH (cis, trans), CF 3C≡C, and C4H9C≡C] with chlorine, bromine, BrF3 + Br2 (as equivalent of "BrF"), and ICl in solution (CH2Cl2, CHCl3, CF 3CH2CF2CH3) led to 1, 2-addition of halogen and/or replacement of boron by halogen (halodeboration). The reaction of [Bu4N][CF3C≡CBF3] with less than equimolar amounts of diluted fluorine (5 %) in 1, 1, 1, 3, 3-pentafluorobutane (PFB) showed only [Bu4N][CF3CF2CF 2BF3] as fluorine addition product besides extensive fluorodeboration. Suspensions of the insoluble K[CF2=CFBF 3] salt reacted with Cl2 and Br2 in CH 2Cl2 giving preferentially products of halogen addition across the C=C bond. In reactions with ICl iododeboration with formation of CF2=CFI occurred besides 1, 2-addition with formation of [CF 2I-CFClBF3]-. The halodeboration reaction of[Bu4N][trans-C4H9CF=CFBF3] with Br2, "BrF", and ICl, of K[trans-C6H 5CF=CFBF3] with Br2, and of [Bu 4N][trans-C4F9CF=CFBF3] with ICl proceeded stereospecifically. Copyright