1361326-28-4Relevant academic research and scientific papers
Phase-transfer-catalyzed enantioselective α-hydroxylation of acyclic and cyclic ketones with oxygen
Sim, Sui-Boon Derek,Wang, Min,Zhao, Yu
, p. 3609 - 3612 (2015)
An efficient and enantioselective α-hydroxylation of acyclic as well as cyclic ketones using molecular oxygen has been developed. This simple catalytic procedure uses a readily available phase-transfer catalyst and produces a wide range of valuable tertia
Rhodium-catalyzed, highly enantioselective 1,2-addition of aryl boronic acids to α-ketoesters and α-diketones using simple, chiral sulfur-olefin ligands
Zhu, Ting-Shun,Jin, Shen-Shuang,Xu, Ming-Hua
scheme or table, p. 780 - 783 (2012/02/06)
Simply the best: The title reaction has been achieved by asymmetric rhodium catalysis employing an extremely simple, chiral N-(sulfinyl)cinnamylamine ligand. A variety of highly enantioenriched, tertiary α-hydroxy carbonyl derivatives were easily accessed
