1361346-21-5Relevant academic research and scientific papers
A coordination compound of Ge0 stabilized by a diiminopyridine ligand
Chu, Terry,Belding, Lee,Van Der Est, Art,Dudding, Travis,Korobkov, Ilia,Nikonov, Georgii I.
, p. 2711 - 2715 (2014)
Reduction of the cationic GeII complex [dimpyrGeCl][GeCl 3] (dimpyr=2,6-(ArN=CMe)2NC5H3, Ar=2,6-iPr2C6H3) with potassium graphite in benzene affords an air sensitive,
Lewis base mediated autoionization of GeCl2 and SnCl2
Singh, Amit Pratap,Roesky, Herbert W.,Carl, Elena,Stalke, Dietmar,Demers, Jean-Philippe,Lange, Adam
, p. 4998 - 5003 (2012/05/05)
Cationic and anionic species of heavier low-valent group 14 elements are intriguing targets in main group chemistry due to their synthetic potential and industrial applications. In the present study, we describe the synthesis of cationic (MCl+) and anionic (MCl3-) species of heavier low-valent group 14 elements of germanium(II) and tin(II) by using the substituted Schiff base 2,6-diacetylpyridinebis(2,6-diisopropylanil) as Lewis base (LB). Treatment of LB with 2 equiv of GeCl2·dioxane and SnCl2 in toluene gives compounds [(LB)GeIICl] +[GeIICl3]- (1) and [(LB)Sn IICl]+[SnIICl3]- (2), respectively, which possess each a low-valent cation and an anion. Compounds 1 and 2 are well characterized with various spectroscopic methods and single crystal X-ray structural analysis.
