1361405-40-4Relevant academic research and scientific papers
A copper thiolate centre for electron transfer: Mononuclear vs. dinuclear complexes
Gennari, Marcello,Pecaut, Jacques,Collomb, Marie-Noelle,Duboc, Carole
, p. 3130 - 3133 (2012/04/10)
We have structurally and spectroscopically investigated a rare example of a mononuclear aliphatic dithiolate CuII complex characterized by a reversible CuII/CuI redox couple. By DFT, we have shown that this system has a lower reorganization energy than its previously described bis(μ-thiolato) dicopper parent complex, which reversibly cycles between the Cu1.5Cu1.5 and CuICuI redox states. The Royal Society of Chemistry 2012.
