136151-74-1Relevant academic research and scientific papers
Reaction of E-1,2-bis[triphenyl(trifluoromethanesulfonyloxy)phospho]ethylene, Ph3PCH=CHPPh3·20Tfwith bases: Unusual products and evidence for C2-dlylide, Ph3P=C=C=PPh3, formation
Stang, Peter J.,Arif, Atta M.,Zhdankin, Viktor V.
, p. 4539 - 4546 (2007/12/18)
E-1,2-di[triphenyl(trifluoromethanesulphonyloxy)phospho]ethylene 4 reacts with Et3N or NaH in wet CH3CN affording phosphineoxides 6 and 7 as a result of phenyl migration and related rearrangements in hydrolysed phosphonium moieties.
