1361598-51-7Relevant academic research and scientific papers
Regioselective Diboration and Silaboration of Allenes Catalyzed by Au Nanoparticles
Kidonakis, Marios,Stratakis, Manolis
, p. 1227 - 1230 (2018)
Under catalysis by commercially available supported Au nanoparticles on TiO2 (1 mol %), terminal allenes undergo diboration and silaboration exclusively on the terminal double bond, in high yields and stereoselectivity. In silaboration, the bor
Stereoselective synthesis of allylsilanes bearing tetrasubstituted olefin via 2,2-Diborylethylsilane
Endo, Kohei,Sakamoto, Akira,Ohkubo, Takahiro,Shibata, Takanori
supporting information, p. 1440 - 1442 (2013/05/08)
The regio-and stereoselective synthesis of allylsilane derivatives bearing a tetrasubstituted olefin was achieved using 2,2-diborylethylsilane as a key intermediate. The regioselective deprotonation of a 2,2-diborylethylsilane with LTMP and the subsequent nucleophilic addition to ketones gave corresponding allylsilanes in good to excellent yield with excellent stereoselectivity.
