1361598-57-3Relevant academic research and scientific papers
Stereoselective synthesis of allylsilanes bearing tetrasubstituted olefin via 2,2-Diborylethylsilane
Endo, Kohei,Sakamoto, Akira,Ohkubo, Takahiro,Shibata, Takanori
, p. 1440 - 1442 (2013/05/08)
The regio-and stereoselective synthesis of allylsilane derivatives bearing a tetrasubstituted olefin was achieved using 2,2-diborylethylsilane as a key intermediate. The regioselective deprotonation of a 2,2-diborylethylsilane with LTMP and the subsequent nucleophilic addition to ketones gave corresponding allylsilanes in good to excellent yield with excellent stereoselectivity.
