136163-26-3Relevant academic research and scientific papers
Reactivity of alicyclic 1,5,9-triketones toward five-, six-, and seven-membered rings in acidic medium. Stereochemistry of intramolecular cyclization products
Akimova, Taisia I.,Soldatkina, Olga A.,Gerasimenko, Andrey V.,Savchenko, Vyacheslav G.,Kapustina, Alevtina A.
, p. 1079 - 1085 (2022/01/11)
[Figure not available: see fulltext.] Among nine alicyclic 1,5,9-triketones with differently fused 5-, 6-, and 7-membered rings in the molecule, existing as mixtures of 3–6 diastereomers, only those containing at least two 6-membered rings were capable of
Methods of synthesis of alicyclic 1,5,9-triketones. Reaction of transaminomethylation
Akimova,Soldatkina,Ivanenko, Zh. A.,Savchenko
, p. 720 - 728 (2017/07/07)
Alicyclic 1,5,9-triketones with various combination of 5-, 6-, 7-membereded cycles in the molecule were obtained by methods of diketone condensation, Michael reaction, and proceeding from Mannich mono- and bisbases and cycloalkanones. The latter method wa
CONDENSATIONS OF ALDEHYDES AND KETONES. XXV. CONDENSATION PRODUCTS OF 2-DIMETHYLAMINOMETHYLCYCLOHEXANONE WITH CYCLOPENTANONE
Akimova, T. I.,Kosenko, S. V.,Tilichenko, M. N.
, p. 2271 - 2277 (2007/10/02)
In the condensation of 2-dimethylaminomethylcyclohexanane with cyclopentanone, in addition to (2-oxocyclohexyl)(2-oxocyclopentyl)-methane, by-products are also formed, namely, 2', 8a-epoxy-4a,5,6,7,8,8a-hexahydrochromane-2-spiro-2'-hydroxycyclohexane and
