13617-38-4

Upstream product

• 4028-23-3 Allylchlorodimethylsilane 
• 100-44-7 benzyl chloride 
• 7439-95-4 magnesium 
• 1833-31-4 benzyl(chloro)dimethylsilane 
• 106-95-6 allyl bromide 

Downstream Products

• 64185-08-6 Benzyl-dimethyl-propyl-silan 
• 135121-02-7 4-[(Benzyl-dimethyl-silanyl)-methyl]-azetidin-2-one 
• 1724-46-5 allyl anion 
• 1842-25-7 fluorodimethyl(phenylmethyl)silane 
• 18860-15-6 phenylmethanide 
• 210362-80-4 allyldimethylfluorosilane 
• 60335-66-2 Nitrosylchlorid des Allyl-benzyl-dimethylsilans 
• 20498-05-9 3-allylcyclohexanone 
• 1261300-61-1 (2E,5E)-methyl 3-allyl-6-(benzyldimethylsilyl)hexa-2,5-dienoate 
• 1261300-58-6 (2E,5E)-ethyl 6-(benzyldimethylsilyl)-3-methylhexa-2,5-dienoate 
• 1261300-50-8 benzyl((1E,4E)-4-benzylideneoct-1-enyl)dimethylsilane 
• 1380233-08-8 (E)-benzyldimethyl(4,4,4-trifluorobut-1-en-1-yl)silane 

Relevant academic research and scientific papers

Zinc mediated allylations of chlorosilanes promoted by ultrasound: Synthesis of novel constrained sila amino acids

A simple, fast and efficient method for allylation and propargylation of chlorosilanes through zinc mediation and ultrasound promotion is reported. As a direct application of the resulting bis-allylsilanes, three novel, constrained sila amino acids are prepared for the first time. The design and synthesis of the constrained sila analogue of GABA (γ-amino butyric acid) is a highlight of this work. This journal is the Partner Organisations 2014.

Copper-catalyzed trifluoromethylation of allylsilanes

CF3 on Csp3: Trifluoromethylation of allylsilane derivatives was accomplished through the use of CuI and Togni's reagent (1) under mild conditions. The reaction of allylsilanes without a substituent in the 2-position gave vinylsilane derivative