136176-67-5Relevant academic research and scientific papers
Diastereocontrol in Intermolecular Diels-Alder Reactions of Allenic Lactones: Synthetic Approach to the Plaunols
Jung, Michael E.,Zimmermann, Craig N.,Lowen, Gregory T.,Khan, Saeed I.
, p. 4453 - 4456 (1993)
Diels-Alder cycloaddition of the allenic lactone 11 with 1-(1-(t-butyldimethylsilyloxy)vinyl)cyclohexene 6b produces the desired cycloadduct 12 with good endo selectivity (4:1) and excellent diastereoselectivity.
