1361952-17-1

Basic information

• Product Name: 2-(1-phenylvinyl)naphthalen-1-amine
• Synonyms: 2-(1-phenylvinyl)naphthalen-1-amine
• CAS NO: 1361952-17-1
• Molecular Weight: 245.324
• Mol File: 1361952-17-1.mol
• Article Data: 15

Chemical Properties

• CAS DataBase Reference: 2-(1-phenylvinyl)naphthalen-1-amine(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(1-phenylvinyl)naphthalen-1-amine(1361952-17-1)
• EPA Substance Registry System: 2-(1-phenylvinyl)naphthalen-1-amine(1361952-17-1)

Safety Data

• Hazardous Substances Data: 1361952-17-1(Hazardous Substances Data)

Upstream product

• 108-86-1 bromobenzene 
• 41048-51-5 1-(1-aminonaphthalen-2-yl)ethan-1-one 
• 134-32-7 1-amino-naphthalene 
• 536-74-3 phenylacetylene 

Downstream Products

• 569344-73-6 3-phenyl-1H-benzo[g]indole 
• 907-43-7 1,3-diphenylphenanthrene 
• 34987-58-1 2,4-diphenylbenzo[h]quinoline 
• 64322-59-4 4-phenylbenzo[h]quinolin-2(1H)-one 
• 31493-10-4 4-phenyl-benzo[h]quinoline 

Relevant articles and documents

Photocatalyzed Intramolecular [2+2] Cycloaddition of N-Alkyl-N-(2-(1-arylvinyl)aryl)cinnamamides

N-Alkyl-N-(2-(1-arylvinyl)aryl)cinnamamides are converted into natural product inspired scaffolds via iridium photocatalyzed intramolecular [2+2] photocycloaddition. The protocol has a broad substrate scope, whilst operating under mild reaction conditions. Tethering four components forming a trisubstituted cyclobutane core builds rapidly high molecular complexity. Our approach allows the design and synthesis of a variety of tetrahydrocyclobuta[c]quinolin-3(1H)-ones, in yields ranging between 20–99 %, and with excellent regio- and diastereoselectivity. Moreover, it was demonstrated that the intramolecular [2+2]-cycloaddition of 1,7-enynes—after fragmentation of the cyclobutane ring—leads to enyne-metathesis-like products.

Mn(III)-Mediated Regioselective 6-endo-trig Radical Cyclization of o-Vinylaryl Isocyanides to Access 2-Functionalized Quinolines

A Mn(III)-mediated radical cyclization reaction of o-vinylaryl isocyanides and arylboronic acids or diphenylphosphine oxides to access various 2-functionalized quinolines under mild conditions was developed. With the introduction of radical stabilizing substituents (e. g. aryl and methyl group) on vinyl group, this reaction provides a regiospecific 6-endo-trig radical cyclization of o-vinylaryl isocyanides, giving a number of structurally unique and biologically potential 2-functionalized quinoline derivatives.

Palladium-Catalyzed/Copper-Mediated Desulfurization and Aryl- ation of Quinoline-2-(1 H)-thione for Rapid Access to Quinoline Derivatives

An efficient method for carbon-carbon bond formation is described. The process employs the palladium-catalyzed and copper-mediated cross-coupling of quinoline-2-(1 H)-thiones with arylboronic acids or alkynes through C-S bond cleavage without an inert atm